期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 57, 期 28, 页码 8674-8677出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201804996
关键词
carbon nitride; organic catalysis; photochemistry; red light
资金
- National Key RAMP
- D Program of China [2018YFA0209301]
- National Natural Science Foundation of China [21425309, 21761132002, 21861130353, 21703039]
- National Postdoctoral Program for Innovative Talents [BX201600031]
- China Postdoctoral Science Foundation [2017M612116]
- 111 Project
Metal-free carbonitride(CN) semiconductors are appealing light-transducers for photocatalytic redox reactions owing to the unique band gap and stability. To harness solar energy efficiently, CN catalysts that are active over a wider range of the visible spectrum are desired. Now a photochemical approach has been used to prepare a new-type triazine-based CN structure. The obtained CN shows extraordinary light-harvesting characteristics, with suitable semiconductor-redox potentials. The light absorption edge of the CN reaches up to 735 nm, which is significantly longer than that of the conventional CN semiconductor at about 460 nm. As expected, the CN can efficiently catalyze oxidation of alcohols and reduction of CO2 with visible light, even under red-light irradiation. The results represent an important step toward the development of red-light-responsive triazine-based structures for solar applications.
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