期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 57, 期 27, 页码 8255-8259出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201802830
关键词
annulation; C-H activation; indolines; rhodium; rhodium shift
资金
- Spanish grants [SAF2016-76689-R, CTQ2016-77047-P]
- Xunta de Galicia [ED431C 2017/19, 2015-CP082, ED431G/09]
- European Regional Development Fund (ERDF)
- European Research Council [340055]
A Rh-III complex featuring an electron-deficient eta(5)-cyclopentadienyl ligand catalyzed an unusual annulation between alkynes and 2-alkenyl anilides to form synthetically appealing 2-substituted indolines. Formally, the process can be viewed as an allylic amination with concomitant hydrocarbonation of the alkyne. Mechanistic experiments indicate that this transformation involves an unusual rhodium migration with a concomitant 1,5-H shift.
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