期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 57, 期 27, 页码 8321-8325出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201802137
关键词
C=C double bond; cumulenes; diradical character; dynamic NMR spectroscopy; rotational barrier
资金
- Deutsche Forschungsgemeinschaft [DFG-SFB 953]
- Natural Sciences and Engineering Research Council of Canada (NSERC)
Bonding is a fundamental aspect of organic chemistry, yet the magnitude of C=C bonding in [n]cumulenes as a function of increasing chain length has yet to be experimentally verified for derivatives longer than n = 5. The synthesis of a series of apolar and unsymmetrically substituted tetraaryl[n]cumulenes (n = 3, 5, 7, 9) was developed and rotational barriers for Z/E isomerization were measured using dynamic VTNMR spectroscopy. Both experiment and theory confirm a dramatic reduction in the rotational barrier (through estimation of Delta G(rot)(double dagger) for the isomerization) across the series, from >24 to 19 to 15 to 11kcal(-1) in [n]cumulenes with n = 3, 5, 7, 9, respectively. The reduction in cumulenic bonding in longer cumulenes thus affords bond rotational barriers that are more characteristic of a sterically hindered single bond than that of a double bond.
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