期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 57, 期 27, 页码 8275-8279出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201805107
关键词
EPR spectroscopy; mercury; mercury-platinum complexes; platinum; radicals
资金
- Israel Science Foundation
- Minerva Foundation in Munich
- German-Israeli project cooperation (DIP)
- Ministry of Immigrant Absorption, State of Israel
The first persistent platinum(I)-centered radical was generated by homolytic cleavage of a Pt-HgSiR3 bond of a mercury-substituted platinum(II) complex. The Pt-1 radical was characterized by EPR spectroscopy, chemical trapping experiments, and density functional theory (DFT) calculations.
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