期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 57, 期 19, 页码 5301-5305出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201801513
关键词
batteries; dendrites; electrolytes; lithium; solvation
资金
- National Natural Scientific Foundation of China [21676160]
- National Key Research and Development Program [2016YFA0200102, 2016YFA0202500]
- China Postdoctoral Science Foundation [BX201700125, 2017M620773]
- Tsinghua National Laboratory for Information Science and Technology
Safe and rechargeable lithium metal batteries have been difficult to achieve because of the formation of lithium dendrites. Herein an emerging electrolyte based on a simple solvation strategy is proposed for highly stable lithium metal anodes in both coin and pouch cells. Fluoroethylene carbonate (FEC) and lithium nitrate (LiNO3) were concurrently introduced into an electrolyte, thus altering the solvation sheath of lithium ions, and forming a uniform solid electrolyte interphase (SEI), with an abundance of LiF and LiNxOy on a working lithium metal anode with dendrite-free lithium deposition. Ultrahigh Coulombic efficiency (99.96%) and long lifespans (1000 cycles) were achieved when the FEC/LiNO3 electrolyte was applied in working batteries. The solvation chemistry of electrolyte was further explored by molecular dynamics simulations and first-principles calculations. This work provides insight into understanding the critical role of the solvation of lithium ions in forming the SEI and delivering an effective route to optimize electrolytes for safe lithium metal batteries.
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