期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 57, 期 18, 页码 5068-5071出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201801817
关键词
aldehydes; alkenes; BrOnsted acids; hydroalkenylation; nickel
资金
- National Natural Science Foundation of China [21672107]
A BrOnsted acid enabled nickel-catalyzed hydroalkenylation of aldehydes and styrene derivatives has been developed. The BrOnsted acid acts as a proton shuttle to transfer a proton from the alkene to the aldehyde, thereby leading to an economical and byproduct-free coupling. A series of synthetically useful allylic alcohols were obtained through one-step reactions from readily available styrene derivatives and aliphatic aldehydes in up to 88% yield and with high linear selectivity.
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