期刊
MACROMOLECULAR SYMPOSIA
卷 360, 期 1, 页码 152-159出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/masy.201500101
关键词
chain transfer; controlled/living radical polymerization; D-limonene; renewable resources; SG1
N-butyl acrylate and D-limonene were copolymerized in bulk via nitroxide-mediated polymerization (NMP) at 115 degrees C using SG1-BlocBuilder. Compared to the free-radical initiation system, the NMP approach resulted in a moderate enhancement to final conversion and slightly higher incorporation of D-limonene into the copolymer microstructure. The copolymer composition using the NMP approach did not differ significantly from that of the free-radical method. A mechanism for the NMP of BA/Lim is proposed which includes a degradative chain transfer reaction due to the allylic hydrogen of D-limonene.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据