4.3 Article

A Colorimetric and Fluorescent Probe for the Detection of Cu2+ in a Complete Aqueous Solution

期刊

ANALYTICAL SCIENCES
卷 34, 期 4, 页码 453-457

出版社

JAPAN SOC ANALYTICAL CHEMISTRY
DOI: 10.2116/analsci.17P517

关键词

Colorimetric probe; fluorescent probe; copper ion (Cu2+); picolinate; internal charge transfer (ICT)

资金

  1. National Science and Technology Support Planning subjects [2015BAD20B02-05]
  2. Municipal Development and Reform Commission Project of Jinan [2016JSFW02Z0307]
  3. Water conservancy science and technology project of Shandong Province [SDSLKY201606]
  4. National Nature Science Foundation of China [21607053, 21107029]
  5. Shandong Province Key Research and Development Project [2016GSF117010]
  6. Outstanding Young Scientists Award Fund of Shandong Province [BS2013HZ007]

向作者/读者索取更多资源

The fluorescent probe has become an important method for the detection of heavy metal ions. In the present work, a new and simple fluorescent probe, Cu-P, for detecting copper ion (Cu2+) was designed and synthesized. The probe has shown high sensitivity and selectivity toward Cu2+. The detection limit was 13 nM (based on the 3 sigma/slope). A significant color change from yellow to pink was observed; thus, the probe Cu-P could serve as a naked-eye indicator for Cu2+. Furthermore, the proposed probe was used to detect Cu2+ in real water and soil extract samples, with the result being satisfactory. Therefore, our proposed probe would provide a promising method for the detection of Cu2+ in the environment.

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