期刊
ANALYTICAL METHODS
卷 10, 期 33, 页码 4063-4072出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ay01080c
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资金
- Science & Engineering Research Board (SERB), Govt. of India [PDF/2016/000334]
- Science & Engineering Research Board (SERB), U.S. [PDF/2016/000080]
- network project BIOCREAM of the Council of Scientific and Industrial Research (CSIR), Govt. of India [ESC103]
The structurally characterized (through single crystal X-ray diffraction) Schiff base ligand N,N-bis(4-methoxy-salicylaldehyde)azine (H(2)SALNN) exhibits poor fluorescence in the excited state, due to rotational (cis/trans) isomerization along the azomethine group. However, in the presence of Cr3+ and Al3+ the isomerization is blocked due to coordination with the metal ions exhibiting turn-on fluorescence. The fluorescence enhancement for Al3+ and Cr3+ at two distinct wavelengths shows much difference of the wavelengths (I = 63 nm). Thus, the selective turn-on fluorescence behaviour of H(2)SALNN for Cr3+ and Al3+ is based on the blocking effect of C?N isomerization and chelation-enhanced fluorescence (CHEF). The coordination modes of the complexes were investigated by spectroscopic and computational studies.
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