期刊
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
卷 17, 期 5, 页码 -出版社
MDPI
DOI: 10.3390/ijms17050670
关键词
ionic liquid; conductivity; density; viscosity; electrolytes
资金
- Deutsche Forschungsgemeinschaft (Sachbeihilfe) [HO 5266/1-1]
- Deutsche Forschungsgemeinschaft
- Karlsruhe Institute of Technology
Temperature-dependent viscosity, conductivity and density data of ternary mixtures containing 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)azanide (EMIM-TFSA), ethylene carbonate (EC), and lithium bis(trifluoromethanesulfonyl) azanide (Li-TFSA) were determined at atmospheric pressure in the temperature range of 20 to 80 degrees C. Differential scanning calorimetry (DSC) measurements were performed to characterize phase conditions of the mixtures in a temperature range of -120 to + 100 degrees C. The viscosity data were fitted according to the Vogel-Fulcher-Tammann-Hesse (VFTH) equation and analyzed with the help of the fractional Walden rule. In this study, fundamental physicochemical data about the mixtures are provided and discussed as a basis for structure-property relationship calculations and for potential use of those mixtures as electrolytes for various applications.
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