期刊
RSC ADVANCES
卷 6, 期 65, 页码 60094-60100出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra08271h
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资金
- Overall Scientific and Technological Innovation Program of Shaanxi Province [2013SZS17-Z01]
- National Science Foundation of Shaanxi Province [2015JM5231]
In this research paper, a series of novel polyimide (PI) foams containing benzimidazole units were prepared derived from polyester ammonium salt (PEAS) precursor powders, which were synthesized by co-polymerization of benzophenone-3,3',4,4'-tetracarboxylic dianhydride (BTDA) with two diamines of 2(4-aminophenyl)-5-aminobenzimidazole (BIA) and 4,4'-diaminodiphenyl ether (ODA) with various molar ratios. The effects of incorporation of BIA on the morphology, thermal and mechanical properties of co-polyimide (co-PI) foams were explored. The results show that the BIA has a significant influence on foaming degree of PEAS precursor powders. The density of co-polyimide foams increases with increasing the BIA content in the polymer chains. Moreover, the thermal stability of the resultant co-polyimide foams presents a remarkable upward trend with incorporating more BIA units into the polymer chains. As the BIA loading up to 30 mol%, the glass transition temperature of co-polyimide foams increases around 50 degrees C in comparison with the pristine polyimide foam. Furthermore, the compressive strength of the co-polyimide foams is in the range of 0.30-0.75 MPa, which is superior to their of commercial polyimide foams with the same density. The co-polyimide foams with higher thermal and mechanical properties expand their potential application in many high-tech fields such as aerospace and aviation industries.
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