期刊
CHEMCATCHEM
卷 8, 期 16, 页码 2581-2588出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201600252
关键词
copper; hydrides; hydroamination; hydrocupration; organocopper
资金
- Slovak Research and Development Agency [APVV-0321-12]
Copper hydride or copper boranyl species have already been used in reactions with Michael acceptors. Recently, notable advances have been described and the methodology extended to unactivated alkenes as well. In situ generated copper hydride ligated with chiral ligands is able to catalyze enantio-selective aminations of alkenes. Furthermore, transient organocopper species formed upon initial hydrocupration of the alkene can be intercepted by other electrophiles such as imines, organohalides, or boranes.
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