期刊
ADVANCED MATERIALS
卷 30, 期 21, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201800855
关键词
dual-source vacuum coevaporation methods; organic solar cells; semitransparent inorganic perovskite solar cells; tandem solar cells; ultraviolet light stability
类别
资金
- National Natural Science Foundation of China [51673138, 91633301]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
- Natural Science Foundation of Jiangsu Province [BK20160059]
- Natural Science Foundation of the Jiangsu Higher Education Institutions of China [16KJB430027]
- China Postdoctoral Science Foundation [2017M610347]
Organic solar cells (OSCs) can be unstable under ultraviolet (UV) irradiation. To address this issue and enhance the power conversion efficiency (PCE), an inorganic-perovskite/organic four-terminal tandem solar cell (TSC) based on a semitransparent inorganic CsPbBr3 perovskite solar cell (pero-SC) as the top cell and an OSC as bottom cell is constructed. The high-quality CsPbBr3 photoactive layer of the planar pero-SC is prepared with a dual-source vacuum coevaporation method, using stoichiometric precursors of CsBr and PbBr2 with a low evaporation rate. The resultant opaque planar pero-SC exhibits an ultrahigh open-circuit voltage of 1.44 V and the highest reported PCE of 7.78% for a CsPbBr3-based planar pero-SC. Importantly, the devices show no degradation after 120 h UV light illumination. The related semitransparent pero-SC can almost completely filter UV light and well maintain photovoltaic performance; it additionally shows an extremely high average visible transmittance. When it is used to construct a TSC, the top pero-SC acting as a UV filter can utilize UV light for photoelectric conversion, avoiding the instability problem of UV light on the bottom OSC that can meet the industrial standards of UV-light stability for solar cells, and leading to the highest reported PCE of 14.03% for the inorganic-perovskite/organic TSC.
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