期刊
ADVANCED FUNCTIONAL MATERIALS
卷 28, 期 10, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201705744
关键词
dual-carbon-modified structures; Sb/C; Sb-O-C bonds; self-thermal reduction; sodium-ion batteries
类别
资金
- National Natural Science Foundation of China [51622406, 21673298, 21473258]
- Project of Innovation Driven Plan in Central South University [2016CX020, 2017CX004]
- China Postdoctoral Science Foundation [2017M6203552]
- National Postdoctoral Program for Innovative Talents [BX00192]
- Hunan Provincial Science and Technology Plan Project [2017TP1001]
Antimony holds a high-specific capacity as a promising anode material for Na-ion batteries (SIBs) and much research is focused on solving the poor cycling stability issue associated with its large volume expansion during alloying/dealloying processes. Here, self-thermal-reduction method is successfully applied to prepare antimony/carbon rods (Sb/C rods) utilizing potassium antimony(III)-tartrate (C8H10O15Sb2K2) as a dual source of carbon matrix and metallic antimony. According to theory calculations and experiment results, the formation process is explicitly explored as follows: C8H10O15Sb2K2 -> Sb2O3/C -> Sb2O3/Sb/C -> Sb/C rods. Notably, organic ligands in C8H10O15Sb2K2 can be gradually turned into amorphous carbon with simultaneous reduction of Sb3+ to metal Sb. Moreover, potassium chloride acts as an activator and a template during the course of carbonization, and synchronous reduction is introduced. Consequently, an antimony/carbon electrode material denoted as Sb-O-C/C is formed, exhibiting a unique dual-carbon-modified structure and extensive Sb-O-C bridge bonds that give rise to outstanding cycling performance and rate capacity. Specifically, the capacity is maintained at 404 mA h g(-1) with 89% retention after 700 cycles at 500 mA g(-1). The low-cost, self-thermal-reduction method and excellent electrode performances of electrode material make it attractive for large-scale energy storage systems.
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