期刊
ACTA MATERIALIA
卷 142, 期 -, 页码 193-200出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.actamat.2017.09.024
关键词
Heusler alloys; Order-disorder phenomena; X-ray diffraction (XRD); Anomalous scattering; Neutron diffraction
资金
- Interuniversity Attraction Poles Program from the Belgian State through the Belgian Policy agency [IAP7/21]
Compounds based on Fe2VAl are good candidates for low grade heat harvesting owing to the thermoelectric effect. However, it is claimed that their thermoelectric properties are badly influenced by antisite defects, especially at higher temperatures. The present study investigates order-disorder transitions in Fe2VAl ternary Heusler compounds. An inherent problem of these compounds is the close atomic numbers of Fe and V, leading to similar x-ray atomic scattering factors. Hence, the 003 and L2(1) structures, corresponding to Fe-V antisite defects, are hardly distinguishable by X-ray diffraction. In this work, anomalous scattering and neutron diffraction were successfully combined with differential scanning calorimetry to highlight the order-disorder transitions in Fe2VAl-based compounds. A model has been developed to quantify the ordering parameters. From these results, specific heat-treatments were defined to promote the formation of the L2(1) ordered phase. (C) 2017 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
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