期刊
ACS NANO
卷 12, 期 3, 页码 2222-2230出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsnano.8b00005
关键词
delignification; wood modification; hierarchical; wetting; composite; mechanical
类别
资金
- Wallenberg Wood Science Center (WWSC)
- China Scholarship Council (CSC)
Tremendous efforts have been dedicated to developing effective and eco-friendly approaches for separation of oil water mixtures. Challenges remain in terms of complex processing, high material cost, low efficiency, and scale-up problems. Inspired by the tubular porosity and hierarchical organization of wood, a strong, mesoporous, and hydrophobic three-dimensional wood structure is created for selective oil/water separation. A delignified wood template with hydrophilic characteristics is obtained by removal of lignin. The delignified wood template is further functionalized by a reactive epoxy amine system. This wood/epoxy biocomposite reveals hydrophobic/oleophilic functionality and shows oil absorption as high as 15 g/g. The wood/epoxy biocomposite has a compression yield strength and modulus up to 18 and 263 MPa, respectively, at a solid volume fraction of only 12%. This is more than 20 times that of cellulose-based foams/aerogels reconstructed from cellulose nanofibrils. The favorable performance is ascribed to the natural hierarchical honeycomb structure of wood. Oil can be selectively absorbed not only from below but also from above the water surface. High oil/water absorption capacity of both types of wood structures (delignified template and polymer-modified biocomposite) allows for applications in oil/water separation.
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