期刊
ACS APPLIED MATERIALS & INTERFACES
卷 10, 期 3, 页码 2480-2489出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.7b15255
关键词
carbon dioxide electroreduction; CO2 solubility; CO2 capture; Faradaic efficiency; gas diffusion electrode
资金
- National Natural Science Foundation of China [21577141, 21576255]
The conversion efficiency and product selectivity of the electroreduction of carbon dioxide have been largely limited by the low CO2 solubility in aqueous solution. To relieve this problem, Cu-3(BTC)(2) (Cu-MOF) as CO2 capture agent was introduced into a carbon paper based gas diffusion electrode (GDE) in this study. The faradaic efficiencies (FEs) of CH4 on GDE with Cu-MOF weight ratio in the range of 7.5-10% are 2-3-fold higher than that of GDE without Cu-MOF addition under negative potentials (-2.3 to -2.5 V vs SCE), and the FE of the competitive hydrogen evolution reaction (HER) is reduced to 30%. This work paves the way to develop GDE with high catalytic activity for ERC.
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