Surface Modification of Silicon Nanoparticles by an Ink Layer for Advanced Lithium Ion Batteries

Owing to its high specific capacity, silicon is considered as a promising anode material for lithium ion batteries (LIBs). However, the synthesis strategies for previous silicon-based anode materials with a delicate hierarchical structure are complicated or hazardous. Here, Prussian blue analogues (PBAs), widely used in ink, are deposited on the silicon nanoparticle surface (PBAs@Si-450) to modify silicon nanoparticles with transition metal atoms and a N-doped carbon layer. A facile and green synthesis procedure of PBAs@Si-450 nano-composites was carried out in a coprecipitation process, combined with a thermal treatment process at 450 degrees C. As-prepared PBAs@Si-450 delivers a reversible charge capacity of 725.02 mAh g(-1) at 0.42 A g(-1) after 200 cycles. Moreover, this PBAs@Si- 450 composite exhibits an exceptional rate performance of, similar to 1203 and 263 mAh g(-1) at current densities of 0.42 and 14 A g(-1) respectively, and fully recovered to 1136 mAh g(-1) with the current density returning to 0.42 A g(-1). Such a novel architecture of PBAs@Si-450 via a facile fabrication process represents a promising candidate with a high-performance silicon-based anode for LIBs.