期刊
ACS APPLIED MATERIALS & INTERFACES
卷 10, 期 6, 页码 5603-5608出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.7b19167
关键词
thermoelectric; mechanochromic luminescence; Organometallic coordination compound; composites; flexible films
资金
- National Natural Science Foundation of China [21402209, 51573190]
- Youth Innovation Promotion Association, Chinese Academy of Sciences [2012024]
We report flexible films of organic-4-inorganic thermoelectric (TE) composites based on organoinetallic coordination compound [copper,phenylacetylide (PhC2Cu),] nanobelts and single-walled-carbon nanotubes (SWCNTO. Interestingly) an unusual mechanochromic luminescence phenomenon from bright green- to-dark red is clearly observed after grinding the PhC2Cu crystalline nanobelts. The PhC2Cu/SWCNT composites display high mechanical flexibility arid.excellent TE performance. The maximum power factor at room temperature can reach as high as 200.2 +/- 10.9 mu W m(-1) K-2. The present study opens an avenue to fabricate novel organic-inorganic TE composite materials using organothetallic coordination compounds such as PhC2Cu.
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