期刊
RSC ADVANCES
卷 6, 期 79, 页码 75376-75383出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra15070e
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资金
- Dongguk University-Seoul
Supercapacitors with solid/gel polymer electrolytes have attracted much attention due to their high reliability, flexibility, facile designing, being separator-free and free from electrolyte leakage and volatilization such that they can meet the increasing demands of practical applications. The present work reports on a functionalized activated carbon (AC) supercapacitor based on novel redox-mediated gel polymer electrolyte, PVA/H3PO4/ionic liquid (1-ethyl-3-methylimidazolium tetrafluoroborate, [EMIM]BF4). The electrochemical properties of this supercapacitor were studied using cyclic voltammetry, galvanostatic charge/discharge and electrochemical impedance spectroscopy techniques with various concentrations of [EMIM]BF4 in PVA/H3PO4 gel polymer electrolyte. The incorporation of [EMIM]BF4 in PVA/H3PO4 electrolyte effectively increased the specific capacitance value due to the improved ionic conductivity and additional pseudo-reaction occurring in the electrode/electrolyte interfaces. The specific capacitance of the supercapacitor using PVA/H3PO4/[EMIM]BF4 (50%) electrolyte showed a maximum value of 271 F g(-1) at 0.5 A g(-1) discharge current, which is much higher than the bare PVA/H3PO4 (103 F g(-1)) based supercapacitor. The supercapacitor with PVA/H3PO4/[EMIM] BF4 (50%) electrolyte showed enhanced energy and power density of 54.3 W h kg(-1) and 23.88 kW kg(-1) respectively. Moreover the device showed comparable specific capacitance retention after 3000 cycles of charge/discharge.
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