4.6 Article

B(C6F5)3 catalysed 1,6-conjugate allylation of para-quinone methides: expedient access to allyl diarylmethanes

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RSC ADVANCES
卷 6, 期 84, 页码 80718-80722

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra19069c

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  1. IISER Mohali
  2. UGC, New Delhi
  3. CSIR, New Delhi

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An effective method for the synthesis of unsymmetrical allyldiaryl methanes is portrayed. This protocol involves a Lewis acid catalysed 1,6-conjugate addition of allyltrimethyl silanes to para-quinone methides, which enabled us to synthesize a variety of unsymmetrical allyl diarylmethanes in good to excellent yields in a very short reaction period.

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