期刊
CHEM
卷 3, 期 6, 页码 1008-1020出版社
CELL PRESS
DOI: 10.1016/j.chempr.2017.10.007
关键词
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资金
- Basic Science Research Program - National Research Foundation under the Korean Ministry of Science, ICT, & Future Planning [2015R1A2A1A10052586, 2017R1A4A1014595]
- US Department of Energy Office of Basic Energy Sciences [DE-FG02-01ER15186]
- Robert A. Welch Foundation [F-0018]
- National Research Foundation of Korea [2015R1A2A1A10052586] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
A meso-aryl calix[4]pyrrole derivative bearing benzimidazolium groups at the two diametrical meso positions was synthesized. The receptor acts as an effective host for the bicarbonate anion at concentrations as low as 4 nM. A change in fluorescence response was observed under conditions of fluorescence dye displacement when this functionalized calix[4]pyrrole was exposed to the HCO3- anion. Tests with various carbonated drinks revealed its ability to function as an easy-to-use sensor for dissolved CO2, as monitored through the bicarbonate anion concentration. Depending on the specific choice of conditions, recrystallization of the calix[4]pyrrole receptor in the presence of Cs2CO3 and methanol yielded crystals of either the HCO3- anion complex or methyl carbonate (CH3OCO2-), a normally difficult-to-access species whose formation under non-forcing equilibrium conditions is ascribed to trapping by the calix[4]pyrrole receptor. The present system thus provides a recognition-based approach to the chemical capture of hydrated, anionic forms of CO2.
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