期刊
NATURE ENERGY
卷 2, 期 8, 页码 -出版社
NATURE PUBLISHING GROUP
DOI: 10.1038/nenergy.2017.111
关键词
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资金
- JEOL Ltd.
- FEI Ltd.
- National 973 Program Project of China [2012CB932800]
- National Natural Science Foundation of China [51572016, 51671145, U1530401]
- National Program for Thousand Young Talents of China
- Tianjin Municipal Education Commission
- Tianjin Municipal Science and Technology Commission
- Fundamental Research Funds of Tianjin University of Technology
- Fundamental Research Funds of Shandong University
Core- shell nanocatalysts have demonstrated potential as highly active low-Pt fuel cell cathodes for the oxygen reduction reaction (ORR); however, challenges remain in optimizing their surface and interfacial structures, which often exhibit undesirable structural degradation and poor durability. Here, we construct an unsupported nanoporous catalyst with a Pt- Pd shell of sub-nanometre thickness on Au, which demonstrates an initial ORR activity of 1.140Amg(Pt)(-1) at 0.9V. The activity increases to 1.471Amg(Pt)(-1) after 30,000 potential cycles and is stable over a further 70,000 cycles. Using aberration-corrected scanning transmission electron microscopy and atomically resolved elemental mapping, the origin of the activity change is revealed to be an atomic-scale evolution of the shell from an initial Pt-Pd alloy into a bilayer structure with a Pt-rich trimetallic surface, and finally into a uniform and stable Pt-Pd-Au alloy. This Pt-Pd-Au alloy possesses a suitable configuration for ORR, giving a relatively low free energy change for the final water formation from adsorbed OH intermediate during the reaction.
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