期刊
CHEMISTRYSELECT
卷 2, 期 1, 页码 51-60出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.201601947
关键词
Biofuel; carbon; furfural; hydrotreatment; 2-methyfuran
资金
- Finnish Funding Agency for Innovation (TEKES) [2653/31/2013]
- Novel Catalysts for Biomass Conversion (CatBio)
In this study inexpensive, non-toxic, and noble metal free mono-and bimetallic catalysts on activated carbon were tested in liquid phase catalytic furfural hydrotreatment to a potential biofuel component 2-methylfuran. High yields of 2-methylfuran were achieved in the study, the highest yield was achieved with 10 wt-% Ni/C (48.9%) in 120 minutes and good results were obtained also with bimetallic 2/2 wt-% CuNi/C and CuFe/C (yield 44.2 and 41.0%, respectively). These high yields were achieved applying significantly shorter reaction time (60 - 120 min) compared to many published studies. The activity of nickel catalysts was very high resulting eventually in further hydrogenation of 2-methylfuran. With increasing nickel loading also ring-opening and decarbonylation reactions were promoted. Addition of iron to nickel was beneficial for decreasing decarbonylation and other side reactions. Copper/nickel and copper/iron combinations were observed to have beneficial interaction as activity and selectivity to MF increased significantly.
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