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Hydrothermal Synthesis of NiCo2O4/Activated Carbon Composites for Supercapacitor with Enhanced Cycle Performance

期刊

CHEMISTRYSELECT
卷 2, 期 18, 页码 5189-5195

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.201700777

关键词

Activated carbon; Electrochemical performance; NiCo2O4 nanoplates

资金

  1. National Natural Science Foundation of China [51202235, 51402276]
  2. Natural Science Foundation [LY15B010004]
  3. Foundation of Science and Technology Department of Zhejiang Province [2016C31113, 2017C33078, 2017C37067]

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Owing to the advantages of the good conductive AC and high capacitive NiCo2O4, We prepared a series of NiCo2O4/AC composites by a hydrothermal method. The morphology of NiCo2O4/AC composites indicate the NiCo2O4 nanoplates with diameters of about 0.5 similar to 1 mm and thickness of about 20 nm are coated on AC. The electrochemical investigation demonstrate that the specific capacitances of NCO-AC-3 (containing 47% NiCo2O4) are 273.5 Fg(-1) and the capacity retention still retains at 96% (262.6 Fg(-1)) after 3000 cycles at current density of 1 Ag-1, especially, the cycling stability maintain more stable at high current density. Therefore, the low-cost NiCo2O4/AC composites can serve as a promising electrode material for high performance supercapacitors due to the synergistic effect between the electric double-layer capacitance of porous AC and the pseudocapacitance of NiCo2O4 nanoplates.

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