期刊
CHEMISTRYSELECT
卷 2, 期 3, 页码 1111-1116出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.201601400
关键词
Coorination polymer; Crystal structure; Lanthanide; Luminescence; magnetic property
资金
- National Natural Science Foundation of China [21371052, 21501050]
- Heilongjiang Postdoctoral Scientific Research Foundation [LBH-Q14138]
- Natural Science Foundation of Heilongjiang University [QL201307]
Two series of twelve polycarboxylate lanthanide coordination polymers (CPs), namely, [Ln(cpida)(H2O)](n){Ln=La (1), Ce (2), Pr (3) and Nd (4)} and {[Ln(cpida)(H2O)]-2H(2)O}(n) {Ln=Sm (5), Eu (6), Gd (7), Tb (8), Dy (9), Ho (10), Er (11) and Yb (12)} {H(3)cpida=N( 4-carboxyphenyl) iminodiacetic acid}, have been synthesized by self-assembly and characterized by IR, TGA, X-ray crystallography, powder XRD and elemental analysis. CPs 1-4 and 5-12 are isomorphic respectively, featuring 2D double layer structures. In CPs 1-4, each metal atom connects five [cpida](3-) anions and each ligand is bound to five metal cations. However, in 5-12 each [cpida](3-) anion only connects four metal cations due to the lanthanide contraction. Further, PL spectra of CPs 6, 8 and 12 show the strong characteristic luminescence of Eu(III), Tb(III) and Yb(III) ions, respectively, suggesting that [cpida](3-) is able to sensitize the luminescence of lanthanide ions efficiently. The magnetic properties of Gd (7) and Dy (9) complexes have also been investigated.
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