期刊
CHEMISTRYSELECT
卷 2, 期 32, 页码 10375-10378出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.201702265
关键词
Annulated arene carbocycle; 1,1-diarylalkene; Friedel-Crafts alkenylation; gem-dihaloalkene; haloalkyne
资金
- IGNTU
- DST-INSPIRE, India [IFA-CH12-79]
- DST-INSPIRE programme
A simple and efficient tactic for the synthesis of gem-hetero- or homo-dihaloalkenes is reported from haloalkynes where Friedel-Crafts alkenylation is a key step. The method provides functionalized tetrasubstituted alkenes which are important precursors in organic synthesis. The strategy is further extended with intramolecular Friedel-Crafts alkenylation on-aryl alkynes to produce annulated arene carbocycles in a simple manner.
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