期刊
CHEMISTRYSELECT
卷 2, 期 32, 页码 10531-10536出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.201702449
关键词
Radical ions; KFL-7; DFT; Photophysical properties; NIR
资金
- JST ERATO [JPMJER1305]
- JSPS KAKENHI [16H04166]
- Grants-in-Aid for Scientific Research [15H01713, 16H04166] Funding Source: KAKEN
The electrochemical properties and electrogenerated chemiluminescence (ECL) of a borondipyrromethane (BODIPY) derivative, 2,8-bis(4-isopropylphenyl)-difuro[2,3-b][3,2-g]-5,5-difluoro-5-bora-3a,4a-diaza-s-indacene (Derivative 1, Figure) are described. Derivative 1 emitted ECL in the range of 650 similar to 800nm by using tripropylamine (TPA) as a coreactant. In the cyclic voltammogram, Derivative 1 showed a reversible oxidation wave, whereas the reduction wave was irreversible. Energetically, it is likely that triplet-triplet annihilation is the main pathway to emit ECL through the ion annihilation of the radical anions and cations of Derivative 1 whereas the lowest excited singlet state of Derivative 1 is directly produced with TPA. The maximum ECL wavelengths (670nm at 0.01mM) were red-shifted with increasing the concentration of Derivative 1 because of the self-absorption resulted from a small Stokes shift (similar to 10nm). Relative ECL efficiency of Derivative 1 was 0.13 compared to that of a Ru(bpy)(2+)/TPA system.
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