期刊
ACS ENERGY LETTERS
卷 2, 期 9, 页码 2149-2156出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsenergylett.7b00620
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资金
- NSF & NIH/NIGMS via NSF Award [DMR-1332208]
- National Science Foundation [ECCS-1549619, CMMI-1537011]
- Princeton Center for Complex Materials funded under NSF-MRSEC [DMR-1420541]
- National Science Foundation (CBET Energy for Sustainability) [CBET-1436875]
- Directorate For Engineering
- Div Of Civil, Mechanical, & Manufact Inn [1536895, 1537011] Funding Source: National Science Foundation
- Div Of Chem, Bioeng, Env, & Transp Sys
- Directorate For Engineering [1436875] Funding Source: National Science Foundation
- Div Of Electrical, Commun & Cyber Sys
- Directorate For Engineering [1549619] Funding Source: National Science Foundation
Recent studies demonstrated that with proper selection of chemically compatible constituents the open-circuit voltage (V-oc) of ternary-blend solar cells can be tuned across the composition window of the active layer. In this study, we probed the limit of the offset between the lowest unoccupied molecular orbital (LUMO) energy levels of the two acceptors in ternary blends containing one donor and two acceptors. We demonstrate, for the first time, that ternary-blend active layers with two acceptors having an energy-level difference between their LUMO levels exceeding 0.4 eV can still result in solar cells exhibiting composition dependent open-circuit voltage (V-oc). Our results suggest strong electronic interactions between the acceptors, with the electron wave function delocalized over multiple molecules. These findings have broadened the library of possible candidates for active layers of ternary-blend solar cells with tunable V-oc, and established guidelines for the design of next-generation materials for efficient performance of such devices.
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