期刊
ACS ENERGY LETTERS
卷 2, 期 10, 页码 2463-2469出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsenergylett.7b00790
关键词
-
类别
资金
- Center for Nanoscale Materials, a U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences User Facility [DE-AC02-06CH11357]
- U.S. National Science Foundation [CBET-1150617]
- U.S. Department of Energy, Office of Science [SC0012541]
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357]
- Office of Science of the U.S. Department of Energy [DE-AC02-05CH11231]
- Directorate For Engineering
- Div Of Chem, Bioeng, Env, & Transp Sys [1150617] Funding Source: National Science Foundation
Solution-processable metal halide perovskites (MHPs) offer great promise for efficient light-harvesting and-emitting devices because of their long carrier lifetime and superior carrier transport properties. Similar to traditional oxide perovskites, MHPs exhibit strong dynamic disorders that may further impact their electronic properties. Here we investigate the coherent acoustic phonons of inorganic and organic inorganic (hybrid) MHP single crystals (CsPbCl3, MAPbCl(3), CsPbBr3, MAPbBr(3), FAPbBr(3), MAPbI(3), and FAPbI(3)) using pump-probe reflection spectroscopy. We show significant phonon softening in the cubic phase of all compositions close to the cubic-to-tetragonal phase transition temperature. Such phonon softening in conjunction with strong acoustic damping is attributed to pretransitional polar fluctuations. Comparison of MHPs with different compositions show that the degree of pretransitional fluctuations is correlated with the size rather than the dipole moment of the A-site cations, and further with the size of the anions.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据