期刊
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
卷 17, 期 9, 页码 -出版社
MDPI
DOI: 10.3390/ijms17091452
关键词
amines; ionic liquids; ionothermal; main-group elements; modifications; polyanions; polycations; starting materials; synthesis parameters; vapor pressure
资金
- DFG (German Science Foundation) [1708]
Ionic liquids (ILs) have been proven to be valuable reaction media for the synthesis of inorganic materials among an abundance of other applications in different fields of chemistry. Up to now, the syntheses have remained mostly black boxes; and researchers have to resort to trial-and-error in order to establish a new synthetic route to a specific compound. This review comprises decisive reaction parameters and techniques for the directed synthesis of polyions of heavy main-group elements (fourth period and beyond) in ILs. Several families of compounds are presented ranging from polyhalides over carbonyl complexes and selenidostannates to homo and heteropolycations.
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