期刊
SCIENCE BULLETIN
卷 62, 期 5, 页码 358-368出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.scib.2017.01.030
关键词
Prussian blue analogues; Energy storage; Rechargeable battery; Open frameworks; Cathode materials; Anode materials; Catalysts
资金
- National 1000 Young Talents Program of China
- National Nature Science Foundation of China [21603078]
- National Materials Genome Project [2016YFB0700600]
- University at Buffalo (Buffalo, New York, United States)
- National Science Foundation, United States [CBET-1511528, 1604392]
- State University of New York (SUNY)
- Div Of Chem, Bioeng, Env, & Transp Sys
- Directorate For Engineering [1604392] Funding Source: National Science Foundation
Prussian blue analogues (PBAs) with open frameworks have drawn much attention in energy storage fields due to their tridimensional ionic diffusion path, easy preparation, and low cost. This review summarizes the recent progress of using PBAs and their derivatives as energy storage materials in alkali ions, multi-valent ions, and metal-air batteries. The key factors to improve the electrochemical performance of PBAs as cathode materials in rechargeable batteries were firstly discussed. Several approaches for performance enhancement such as controlling the amounts of vacancies and coordinated water, optimizing morphologies, and depositing carbon coating are described in details. Then, we highlighted the significance of their diverse architectures and morphologies in anode materials for lithium/sodium ion batteries. Finally, the applications of Prussian blue derivatives as catalysts in metal-air batteries are also reviewed, providing insights into the origin of favorable morphologies and structures of catalyst for the optimal performance. (C) 2017 Science China Press. Published by Elsevier B.V. and Science China Press. All rights reserved.
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