期刊
ORGANIC CHEMISTRY FRONTIERS
卷 4, 期 1, 页码 95-100出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6qo00530f
关键词
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资金
- Natural Science Foundation of China [21502069]
- Natural Science Foundation of Zhejiang Province [LQ15B020006]
- Ph.D. Scientific Research Starting Foundation of Jiaxing University [70515015]
- Shanghai Ocean University [A2-0203-00-100338]
A bismuth(III) chloride-mediated one-pot reaction of anilines, sulfur dioxide, and trifluoromethanesulfanylamide is reported herein, leading to antifungal trifluoromethyl thiolsulphonates. This transformation employs N-aminomorphine as an additive and provides the final products in good yields with a broad functional group tolerance. It is believed that bismuth(III) chloride facilitates the formation of CF3S+, and N-aminomorphine plays a critical role in providing electrons to catalyse the cross-coupling of in situ generated aryldiazonium, sulfur dioxide and trifluoromethanesulfanylamide.
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