tert-Butyl nitrite-mediated vicinal sulfoximation of alkenes with sulfinic acids: a highly efficient approach toward α-sulfonyl ketoximes

A novel vicinal sulfoximation of alkenes was achieved under mild and metal-free conditions by using readily available sulfinic acids as the sulfonating agent and tert-butyl nitrite (TBN) as the radical initiator and the oxime source. Various structurally important alpha-sulfonyl ketoximes can be prepared from unactivated as well as activated alkenes in high efficiency by utilizing this protocol.