期刊
ORGANIC CHEMISTRY FRONTIERS
卷 4, 期 10, 页码 2044-2048出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7qo00490g
关键词
-
资金
- National Natural Science Foundation of China [21572075]
- 111 Project [B17019]
The multifunctional odorless isocyano(triphenylphosphorany-lidene) acetate was prepared as a new stable phosphorus ylide containing isocyanide group. A new one-pot four component synthesis of multi-substituted oxazoles by a cascade Ugi/Wittig process without Mumm rearrangement has been developed, starting from the isocyano(triphenylphosphora-nylidene) acetates, aldehydes, amines and acids. Two component reactions of isocyano(triphenylphosphoranylidene)-acetates and acids also generated disubstituted oxazoles in good yields.
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