期刊
ORGANIC CHEMISTRY FRONTIERS
卷 4, 期 6, 页码 1042-1045出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6qo00675b
关键词
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资金
- National Natural Science Foundation of China [20972134]
- Zhejiang Provincial Natural Science Foundation of China [LY14B020008]
beta-Sulfonium carbanions, members of the organosulfur family, are ephemeral intermediates and difficult to apply in organic syntheses. We developed a new strategy toward relatively stable beta-sulfonium carbanions, achieved by an intramolecular addition of the sulfur atom of a sulfide to the in situ generated electron-deficient allene moiety. These types of applicable beta-sulfonium carbanions may indicate an unexplored area in which a bundle of synthetically useful building blocks are yet to be discovered.
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