期刊
ORGANIC CHEMISTRY FRONTIERS
卷 4, 期 3, 页码 417-420出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6qo00663a
关键词
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资金
- National Natural Science Foundation of China [21402168]
- Scientific Research Foundation of Hunan Provincial Education Department [15B232]
- NSERC
- FQRNT
- CFI
- Canada Research Chair
The development of an efficient and practical synthetic approach for the regiospecific C-H ortho-phenylation of aromatic carboxylic acids without the use of silver or costly coupling partners is reported. The rhodium-catalyzed C-H phenylation proceeded in the presence of Cu/air as a terminal oxidant. In most cases, numerous inactivated benzoic acids could couple with low-cost NaBPh4 to obtain good to excellent yields.
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