期刊
ORGANIC CHEMISTRY FRONTIERS
卷 4, 期 12, 页码 2291-2295出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7qo00769h
关键词
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资金
- Recruitment Program of Global Experts (1000 Talents Plan)
- Natural Science Foundation of Fujian Province [2016J01064]
- Program of Innovative Research Team of Huaqiao University [Z14X0047]
An efficient, convenient and mild Ru-catalyzed reductive amination reaction was developed by employing H2O as both hydrogen source and solvent via B-2(OH)(4)/H2O systems. The reaction proceeded smoothly under air at ambient temperature and exhibited excellent chemoselectivities toward unsaturated and heteroaromatic as well as aliphatic aldehydes. Interestingly, a-deuterated amines were also obtained expediently by employing D2O in our catalytic systems.
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