期刊
ORGANIC CHEMISTRY FRONTIERS
卷 4, 期 11, 页码 2235-2255出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7qo00614d
关键词
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资金
- National Natural Science Foundation of China [21602022, 81620108027, 21632008]
- Major Project of Chinese National Programs for Fundamental Research and Development [2015CB910304]
- Open Project Program of Key Laboratory of Medicinal and Edible Plants Resources Development of Sichuan Education Department [10Y201711]
The diboration of alkynes has become the most straightforward and powerful method for the synthesis of functionalized 1,2-diborylalkenes, which are widely used as building blocks in organic synthesis. The present review provides a comprehensive summary of the diboration of alkynes, including platinum-, palladium-, cobalt-, copper-, iridium-, gold-, iron-, base- and small organic molecule-catalyzed diboration, direct and metal-free diboration, and base- promoted diboration of alkynes up to early 2017. The reaction conditions, regio- and stereoselectivities, and mechanisms are summarized in detail. Moreover, synthetic applications and perspectives on the diboration of alkynes are also discussed.
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