期刊
ORGANIC CHEMISTRY FRONTIERS
卷 4, 期 10, 页码 2031-2033出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7qo00459a
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资金
- National Natural Science Foundation of China [21290180, 21472210, 21672243]
- Youth Innovation Promotion Association CAS [2012202]
The asymmetric total synthesis of (-)-patchouli alcohol was accomplished in a concise manner. Key reactions include a highly diastereo- and enantioselective formal organocatalytic [4 + 2] cycloaddition reaction, a radical denitration reaction, and an oxidative carboxylation reaction. The formal synthesis of norpatchoulenol was achieved as well.
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