期刊
NATIONAL SCIENCE REVIEW
卷 5, 期 6, 页码 907-919出版社
OXFORD UNIV PRESS
DOI: 10.1093/nsr/nwx127
关键词
porous coordination polymers; metal-organic frameworks; flexibility; dynamism; adsorption; structural transformation
资金
- National Basic Research Program of China [2014CB845602]
- National Natural Science Foundation of China [21290173, 21473260]
Framework flexibility is one of the most important characteristics of metal-organic frameworks (MOFs), which is not only interesting, but also useful for a variety of applications. Designing, tailoring or controlling framework flexibility of MOFs is much more difficult than for static structural features such as the framework topology and pore size/shape. Nevertheless, with in-depth understanding of the relationship between framework flexibility and the host framework structure, guest loading and other aspects such as the crystal size/morphology and external physical environment, some strategies have been developed for controlling the flexibility of MOFs and the corresponding properties, which are summarized and discussed in this review.
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