期刊
CHINESE JOURNAL OF CATALYSIS
卷 37, 期 12, 页码 2098-2105出版社
SCIENCE PRESS
DOI: 10.1016/S1872-2067(16)62558-5
关键词
Mesoporous silica; Phosphomolybdic acid; Oxidative desulfurization; Benzothiophene; Dibenzothiophene
资金
- National Natural Science Foundation of China [21473126]
A highly active catalyst of phosphomolybdic acid (HPMo) was prepared and applied in the catalytic oxidative desulfurization (CODS) system. The catalyst was characterized by FT-IR, XRD, XPS and superconducting NMR. The influences of m(catalyst)/m(oil), V(H2O2)/V(oil), reaction temperature and reaction time on the fractional conversion of benzothiophene (BT) and dibenzothiophene (DBT) were investigated. GC-MS and micro-coulometric methods were employed to investigate the reaction. The catalyst has high desulfurization activity in the removal of BT and DBT under mild conditions. The recycling experiments indicated that DBT and BT removal could still reach 95.2% and 95.7% after 10 cycles. (C) 2016, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
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