期刊
INORGANIC CHEMISTRY FRONTIERS
卷 4, 期 12, 页码 2068-2074出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7qi00457e
关键词
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资金
- Basic Science Research Program through the National Research Foundation of Korea (NRF)
- Ministry of Education [2010-0020207, 2016R1D1A1B01015047]
- MOTIE [10052928]
- KSRC (Korea Semiconductor Research Consortium)
- Nano Material Technology Development Program through the National Research Foundation of Korea (NRF) - Ministry of Science, ICT and Future Planning [2015 M3A7B7045194, 2016 M3A7B4909942]
- Korea Evaluation Institute of Industrial Technology (KEIT) [10052928] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
- National Research Foundation of Korea [2015M3A7B7045125, 2010-0020207, 2016M3A7B4909942] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Herein, we demonstrate the synthesis of molybdenum disulphoselenide (MoS2(1-x)Se2x) and tungsten disulphoselenide (WS2(1-x)Se2x) alloys onto FTO substrates, to obtain a higher hydrogen evolution reaction (HER) activity compared to pristine MoS2 and WS2. By incorporating selenium (Se) into MoS2 and WS2 matrices, an excellent HER catalytic activity was ensured in an acidic electrolyte with overpotentials of 141 mV and 167 mV @ 10 mA cm(-2) with Tafel slopes of 67 and 107 mV per decade for MoS2(1-x)Se2x and WS2(1-x)Se2x, respectively. Moreover, MoS2(1-x)Se2x and WS2(1-x)Se2x alloys showed robust durability over 20 h of continuous HER operation in acidic solutions. Our investigation provides the synthesis of tunable metal dichalcogenide hybrid structures with better electrochemical performance.
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