期刊
INORGANIC CHEMISTRY FRONTIERS
卷 4, 期 9, 页码 1445-1450出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7qi00300e
关键词
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资金
- National Natural Science Foundation of China [21471032]
- Project 973 [2014CB848800]
- Fundamental Research Funds for the Central Universities
A new organic-inorganic hybrid compound [(CH3)(3)PCH2OH][Cd(SCN)(3)] (1) has been synthesized, which exhibits a reversible phase transition at 248.5 K confirmed by differential scanning calorimetry. The phase transition in 1 is from a centrosymmetric space group Pmcn to a non-centrosymmetric space group P2(1), so that 1 exhibits a switchable second harmonic generation (SHG) effect between SHG-on and SHG-off states. This phase transition also displays switchable dielectric behaviors between high and low dielectric states accompanied by the remarkable dielectric relaxation described by the Cole-Cole equation. Variable-temperature single-crystal X-ray diffraction analyses reveal that the origin of the phase transition can be attributed to the motion or reorientation of the [(CH3)(3)PCH2OH] cations and the movement of (SCN)-ions in solid-state crystals. These superior physical properties suggest that 1 could be a potential switchable dielectric and NLO relaxor-type material, which provides a new approach to design novel multiple switch materials.
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