期刊
INORGANIC CHEMISTRY FRONTIERS
卷 4, 期 4, 页码 701-705出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6qi00543h
关键词
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资金
- National Natural Science Foundation of China [21222208, 21321001, 91422302, 21421091, 21432001]
- National Key Basic Research Program of China [2013CB933401, 2011CB808705]
A series of tetrahedral Co(II) complexes with chalcogen donors were prepared, which exhibited strong magnetic uniaxial anisotropies and slow relaxations as SIMs. By substituting donors from S to Te, we realized the fine-tuning of the ligand field while keeping the coordination geometry virtually unchanged, yielding the first tellurium-coordinated SIM.
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