期刊
CHEMCATCHEM
卷 8, 期 21, 页码 3361-3366出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201600785
关键词
arenes; oxidation; oxygen; radicals; reaction mechanisms
资金
- Program for Science & Technology Innovation Talents in Universities of Henan Province [15HASTIT004]
- State Key Laboratory for Oxo Synthesis and Selective Oxidation [OSSO-2015-21]
NO2 is an effective catalyst for the oxidative thiocyanation of arenes. This unique catalyst is inexpensive and separated easily from the final products because of its low boiling point. The mild reaction conditions allow a series of arenes and thiophenes to be thiocyanated smoothly in moderate to high yields. A preliminary mechanistic investigation suggests that the present reaction may proceed through a radical pathway.
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