4.6 Article

High-Throughput Small-Molecule Crystallography at the Belok' Beamline of the Kurchatov Synchrotron Radiation Source: Transition Metal Complexes with Azomethine Ligands as a Case Study

期刊

CRYSTALS
卷 7, 期 11, 页码 -

出版社

MDPI AG
DOI: 10.3390/cryst7110325

关键词

Kurchatov synchrotron radiation source; transition metals; azomethine ligands; secondary interactions; crystal structure

资金

  1. Ministry of Education and Science of the Russian Federation [4.5388.2017/8.9, RFMEFI61917X0007]
  2. RUDN University Program [5-100]

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This paper concisely describes capabilities of the Belok' beamline at the Kurchatov synchrotron radiation source, related to high-throughput small-molecule X-ray crystallography. As case examples, a series of four novel transition metal complexes with azomethine ligands were selected. The complexes demonstrate somewhat unexpected changes in the coordination geometry and nuclearity in response to the introduction of substituents in the ligand's periphery.

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