期刊
ADVANCED SCIENCE
卷 4, 期 10, 页码 -出版社
WILEY
DOI: 10.1002/advs.201700247
关键词
hollow structures; MOF composites; oxygen reduction reaction; single-holed particles; ZIF-67
资金
- National Research Foundation (NRF) of Singapore [NRF-NRFI2016-04]
Design and construction of metal-organic framework (MOF) composite precursors have recently been considered as a promising strategy for the preparation of different structured metal/carbon-based functional materials. Here, an MOF composite-assisted strategy to synthesize single-holed cobalt/N-doped carbon hollow particles is reported. The yolk-shell polystyrene@zeolitic imidazolate framework-67 (PS@ZIF-67) composite precursors are first synthesized, followed by a controlled pyrolysis to obtain cobalt/N-doped carbon hollow particles with a large single hole on each shell. Moreover, the MOF-coating approach reported in this work can be extended to prepare various core-shell ZIF-67 composites with different structures and compositions. Benefiting from the structural and compositional advantages, the as-derived single-holed cobalt/N-doped carbon hollow particles manifest superior electrocatalytic oxygen reduction performance with high activity and excellent durability.
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