期刊
21ST EUROPEAN CONFERENCE ON FRACTURE, (ECF21)
卷 2, 期 -, 页码 2405-2414出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.prostr.2016.06.301
关键词
polymer degradation; mechanical properties; radiation and thermal ageing; EPDM
The mechanical properties of industrial and neat Ethylene Propylene Diene Monomer (EPDM) polymers, aged under gamma-irradiation at different temperatures, are studied. The focus is given to the dose rate effects in polymer insulation materials, so the ageing is performed in the wide range of dose rates, doses and temperatures. Industrial EPDM samples are extracted from the cables in use in Belgian Nuclear Power Plants (NPP), and the neat EPDM samples are produced in the laboratory. The mechanical tests of non-aged and aged polymers are performed, and the methodology of estimating the polymer life time is discussed. The ultimate tensile stress and elongation at break are found to be strongly affected by both irradiation condition and temperature. The ultimate tensile stress clearly exhibits the dose rate effect observed through the shift of the crossover between cross-linking to chain scission process as a function of the dose. This crossover shifts to high dose for large dose rates, while the opposite is observed by increasing the temperature. Dose rate effect is less evident in the elongation at break data, probably because both cross-linking and chain scission affect the elongation at break in the same way, by decreasing it. In comparison to industrial EPDM aged under the same conditions, the cross-linking to chain scission crossover appears at lower dose in neat polymer and the elongation at break decreases faster by increasing the dose. In addition, the elongation at break experimental results can be modeled by changing single parameter, namely pre-exponential factor of the irradiation rate constant. This confirms that both aging processes, cross-linking and chain scission affect the elongation at break in a similar way, by deteriorating network structure responsible for polymer elastic properties. Irradiation rate constant is found to follow the square root dependence for industrial EPDM, while the linear dependence is observed for the neat EPDM. This indicates the existence of different degradation processes in these two polymers. (C) 2016 The Authors. Published by Elsevier B.V.
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