4.6 Article

Phenyl Derivative of Dibenzothiopheno[6,5-b:6′,5′-f]-Thieno[3,2-b]Thiophene (DPh-DBTTT): High Thermally Durable Organic Semiconductor for High-Performance Organic Field-Effect Transistors

期刊

ADVANCED ELECTRONIC MATERIALS
卷 3, 期 10, 页码 -

出版社

WILEY
DOI: 10.1002/aelm.201700142

关键词

organic semiconductors; organic thin-film transistors; single-crystal field-effect transistors

资金

  1. Global Leading Technology Program - Ministry of Trade, Industry, and Energy, Republic of Korea [10042419]
  2. Center for Advanced Soft Electronics [2013M3A6A5073175]
  3. National Research Foundation of Korea of the Ministry of Science, ICT & Future Planning, Korea [2014R1A2A2A01007467]
  4. Korea Evaluation Institute of Industrial Technology (KEIT) [10042419, 10042537] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
  5. National Research Foundation of Korea [2013M3A6A5073175, 2014R1A2A2A01007467] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

向作者/读者索取更多资源

Phenyl-substituted heteroacene, diphenyl-dibenzothiopheno[6,5-b:6',5'-f]-thieno[3,2-b]thiophene (DPh-DBTTT), is introduced as a thermally durable high-performance organic semiconductor. The DPh-DBTTT single crystals exhibit hole mobility up to 31.9 cm(2) V-1 s(-1), and the vacuum-deposited DPh-DBTTT thin-film transistors show a maximum mobility of 6.32 cm(2) V-1 s(-1). X-ray crystallographic analysis reveals that the small tilting angle between the phenyl substituent and the DBTTT core reduces the reorganization energy dramatically. The structure-property relationships are thoroughly investigated using atomic force microscopy, transmission electron microscopy, and grazing incidence X-ray diffraction analyses, in addition to charge-transport studies. The vacuum-deposited DPh-DBTTT thin-film transistors show superior thermal durability compared to the core DBTTT, which is highly valuable for device processability.

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